Polymer Chemistry, Physics and Self-Organization

The research in the Kristoffer Almdal Group is dedicated to the design and synthesis of polymer molecules that enable tailored solutions to challenges in materials science. A central theme is artificial self-organization, inspired by natural systems, where molecular incompatibilities and connections are exploited to guide self-assembly in soft matter near phase transitions. This fundamental knowledge is coupled with innovative fabrication methods, including advanced 3D printing, to develop structured materials with defined functions.

Research

In our group, research activities are centered on molecular design, synthesis, and the study of self-assembly processes in polymeric systems. Block copolymers, both linear and branched, serve as the main building blocks for investigating how phase separation and molecular connectivity can be tuned to yield specific morphologies. A major application area is the 3D structuring of materials, with a particular emphasis on tomographic 3D vat printing. This technique employs multi-directional light patterning and multi-wavelength illumination to achieve high-resolution architectures with tunable properties.

Our core competence lies in identifying and synthesizing polymers that meet specific functional requirements, often in collaboration with researchers from other disciplines. Self-organization in these systems arises from a delicate balance between separation forces and molecular connections—an interplay reminiscent of natural processes. We use block copolymers — linear and branched — in the study of the fundamental principles governing self-organization. By fine-tuning molecular building blocks and operating close to phase transition conditions, the group explores new routes to self-organized materials.

We engage in interdisciplinary collaborations to identify new applications for their materials, with particular interest in biomedical and soft robotic systems, and other advanced technologies where precision-structured polymers can play a transformative role.

The Figure illustrates a small-angle neutron scattering experiment on a stretched polystyrene polymer melt. Results published in Rheologica Acta, 51 (2012)

Research Highlights:

Block copolymer Self organization:

Macromolecules, 25 (1992); Macromolecules, 28 (1995); PRL, 65 (1990); J Polymer Science 56 (2018)

Extensional Flow in polymer melts:

Macromolecules, 36 (2003); PRL, 120 (2018)

Polymer Degradation:

Polym. Degradation and Stability 83 (2004)

Structured surfaces:

Nano Research 7 (2014); ACS Applied Materials & Interfaces, 8 (2016)

Profile

2008- Professor in Polymers in micro- and Nanotechnology

2003-2007 Head of Department, Danish Polymer Centre, Risø National Laboratory

1989 PhD in Polymer Chemistry, University of Copenhagen

1985 MSc in Physical Organic Chemistry, University of Copenhagen

Elected member of the Danish Academy of Natural Sciences (DNA, 2002).

Elected member of the Danish Academy of Technical Sciences (ATV, 2012).

Recipient of the 2012 ATV|Elastyren Prize

News

2019

1 January: Joined the faculty at DTU Chemistry

2018

3 Oktober: A joint effort between DTU, Oak Ridge National Laboratory, Tennessee, USA, Niels Bohr Institute, University of Copenhagen, Denmark, and University of Massachusetts Amherst, USA on self-organized 3 arm stars -so called mikto-arm stars discovers new surface structures.

The results are  published in late 2018 (Sergey Chernyy, Jyoti P. Mahalik, Rajeev Kumar, Jacob Judas Kain Kirkensgaard, Matthias M. L. Arras, Hyeyoung Kim, Lars Schulte, Sokol Ndoni, Gregory S. Smith, Kell Mortensen, Bobby G. Sumpter, Thomas P. Russell, Kristoffer Almdal: On the Morphological Behavior of ABC Miktoarm Stars Containing Poly(cis 1,4-isoprene), Poly(styrene) and Poly(2-vinylpyridine). Journal of Polymer Science, Part B: Polymer Physics, 56, 1491-1504 (2018)/doi:10.1002/polb.24733)

2017

3-7 April: Kristoffer Almdal is co-organizing the 2017 annual European Rheology Conference.